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Molar refractivity : ウィキペディア英語版
Molar refractivity
Molar refractivity, A, is a measure of the total polarizability of a mole of a substance and is dependent on the temperature, the index of refraction, and the pressure.
The molar refractivity is defined as
: A = \frac N_A \alpha,
where N_A \approx 6.022 \times 10^ is the Avogadro constant and \alpha is the mean polarizability of a molecule.
Substituting the molar refractivity into the Lorentz-Lorenz formula gives
: A = \frac \frac
For a gas, n^2 \approx 1, so the molar refractivity can be approximated by
:A = \frac \frac.
In SI units, R has units of J mol−1 K−1, T has units K, n has no units, and p has units of Pa, so the units of A are m3 mol−1.
In terms of density, ρ molecular weight, M it can be shown that:
:A = \frac \frac \approx \frac \frac.
==References==

* Born, Max, and Wolf, Emil, ''Principles of Optics: Electromagnetic Theory of Propagation, Interference and Diffraction of Light'' (7th ed.), section 2.3.3, Cambridge University Press (1999) ISBN 0-521-64222-1

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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